The two systems are very similar with many of the same advantages that make Solarlux bifolds about the best available.
The Highline, however, has a slightly thicker profile (front to back). This has a number of advantages. It enables thicker glass profiles, particualty when triple-glazing is required for better thermal performance or increased sound insulation.
It also enables larger panels so if you are looking for wider panels, then Highline would be the solution.
In many cases, however, Ecoline is perfect.
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